Single subduction zone for the generation of Devonian ophiolites and high‐P metamorphic belts of the Variscan Orogen (NW Iberia)     

Rubn Díez Fernndez  Ricardo Arenas  Sonia Snchez Martínez  Irene Novo‐Fernndez  Richard Albert 《地学学报》2020,32(4):239-245

Within the Variscan Orogen, Early Devonian and Late Devonian high‐P belts separated by mid‐Devonian ophiolites can be interpreted as having formed in a single subduction zone. Early Devonian convergence nucleated a Laurussia‐dipping subduction zone from an inherited lithospheric neck (peri‐Gondwanan Cambrian back‐arc). Slab‐retreat induced upper plate extension, mantle incursion and lower plate thermal softening, favouring slab‐detachment within the lower plate and diapiric exhumation of deep‐seated rocks through the overlying mantle up to relaminate the upper plate. Upper plate extension produced mid‐Devonian suprasubduction ocean floor spreading (Devonian ophiolites), while further convergence resulted in plate coupling and intraoceanic ophiolite imbrication. Accretion of the remaining Cambrian ocean heralded Late Devonian subduction of inner sections of Gondwana across the same subduction zone and the underthrusting of mainland Gondwana (culmination of NW Iberian allochthonous pile). Oblique convergence favoured lateral plate sliding, and explained the different lateral positions along Gondwana of terranes separated by Palaeozoic ophiolites.  相似文献   

Subsidence and thermal history of an inverted Late Jurassic‐Early Cretaceous extensional basin (Cameros,North‐central Spain) affected by very low‐ to low‐grade metamorphism          下载免费PDF全文

Silvia Omodeo‐Salé  Ramon Salas  Joan Guimerà  Robert Ondrak  Ramon Mas  José Arribas  Isabel Suárez‐Ruiz  Luis Martinez 《Basin Research》2017,29(Z1):156-174

The Cameros Basin (North Spain) is a Late Jurassic‐Early Cretaceous extensional basin, which was inverted during the Cenozoic. It underwent a remarkable thermal evolution, as indicated by the record of anomalous high temperatures in its deposits. In this study, the subsidence and thermal history of the basin is reconstructed, using subsidence analysis and 2D thermal modelling. Tectonic subsidence curves provide evidence of the occurrence of two rapid subsidence phases during the syn‐extensional stage. In the first phase (Tithonian‐Early Berriasian), the largest accommodation space was formed in the central sector of the basin, whereas in the second (Early Barremian‐Early Albian), it was formed in the northern sector. These rapid subsidence phases could correspond to relevant tectonic events affecting the Iberian Plate at that time. By distinguishing between the initial and thermal subsidence and defining their relative magnitudes, Royden's (1986) method was used to estimate the heat flow at the end of the extensional stage. A maximum heat flow of 60–65 mW/m² is estimated, implying only a minor thermal disturbance associated with extension. In contrast with these data, very high vitrinite reflectance, anomalously distributed in some case with respect to the typical depth‐vitrinite reflectance relation, was measured in the central‐northern sector of the basin. Burial and thermal data are used to construct a 2D thermal basin model, to elucidate the role of the processes involved in sediment heating. Calibration of the thermal model with the vitrinite reflectance (%Ro) and fluid inclusion (FI) data indicates that in the central and northern sectors of the basin, an extra heat source, other than a typical rift, is required to explain the observed thermal anomalies. The distribution of the %Ro and FI values in these sectors suggests that the high temperatures and their distribution are related to the circulation of hot fluids. Hot fluids were attributed to the hydrothermal metamorphic events affecting the area during the early post‐extensional and inversion stages of the basin.  相似文献   

Early Ordovician (Floian) ostracods from the Cordillera Oriental,Northwest Argentina     

María Jos Salas 《Geological Journal》2011,46(6):637-650

The ostracod fauna from the Floian (Lower Ordovician) strata of the Cordillera Oriental, Argentina (Acoite Formation) are documented. One new genus Acoitella and four species are recognized, two of which are new (Nanopsis victoria sp. nov. and Conchoprimitia frequens sp. nov.). The diversity of the Early Ordovician ostracod faunas of the Central Andean Basin is evaluated. Compared with other regions, the ostracod diversity, at generic and specific level, of the Cordillera Oriental was comparatively high during the Tremadocian (nine species recorded) and comparatively low during the Floian (four species recorded). The taxonomic composition of the fauna is similar during the entire Early Ordovician of the Cordillera Oriental, where it displays a high percentage of soanellids. The Floian assemblages are characterized by the dominance of the eridostracan C. frequens sp. nov. with a high percentage of nondimorphic palaeocopids: Nanopsis and two genera of the Soanellidae family (Saltite and Acoitella gen nov.). An ostracod shell bed is described and interpreted to be a parautochthonous assemblage, as a result of transport within the same habitat. The composition of the fauna, with the presence of Saltite and Nanopsis, shows significant affinities with East Gondwana. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

Sulfur Determination in Geological Samples Based on Coupled Analytical Techniques: Electric Furnace-IC and TGA-EGA     

Maria F. Gazulla  Maria P. Gómez  Mónica Orduña  Eulalia Zumaquero  Sonia Vicente 《Geostandards and Geoanalytical Research》2009,33(1):71-84

A study has been undertaken to determine sulfur in geological samples by coupled analytical techniques. Two measurement methods have been developed: one using an electric furnace coupled to an ion chromatograph (electric furnace-IC) and another using infrared (IR) and quadrupole mass spectrometry (QMS) for evolved gas analysis (EGA) coupled with a thermogravimetric analyser (TGA). In the electric furnace-IC method, measurement was performed without any sample pre-treatment. The measurement conditions were optimised by varying sample quantity, type of catalyst (WO₃, Cu, W and V₂O₅) and sample/catalyst ratio, and the detection limit was 10 μg g⁻¹. Sulfur ores decompose at different temperatures. However, TGA-EGA allowed identification of the different forms of sulfur in the sample, even when they were found in very low concentrations, because the sulfur was continuously analysed. The developed chromatographic method allowed simultaneous analysis of several sample components, such as S, Cl and F, with a low detection limit. The method was much faster and more specific than the methods described in the literature. The results of the sulfur determination had low scatter, possibly because the samples underwent little handling during analysis: the operator only weighed and placed the sample in the furnace, the rest of the measurement process was fully automated. The results obtained by both the developed methods have been validated by using reference materials and comparison with combustion-IR spectroscopy, a standard method for determining total sulfur in a sample.  相似文献   

COSMO-CLM2: a new version of the COSMO-CLM model coupled to the Community Land Model     

Edouard L. Davin  Reto St?ckli  Eric B. Jaeger  Samuel Levis  Sonia I. Seneviratne 《Climate Dynamics》2011,37(9-10):1889-1907

This study presents an evaluation of a new biosphere-atmosphere Regional Climate Model. COSMO-CLM² results from the coupling between the non-hydrostatic atmospheric model COSMO-CLM version 4.0 and the Community Land Model version 3.5 (CLM3.5). In this coupling, CLM3.5 replaces a simpler land surface parameterization (TERRA_ML) used in the standard COSMO-CLM. Compared to TERRA_ML, CLM3.5 comprises a more complete representation of land surface processes including hydrology, biogeophysics, biogeochemistry and vegetation dynamics. Historical climate simulations over Europe with COSMO-CLM and with the new COSMO-CLM² are evaluated against various data products. The simulated climate is found to be substantially affected by the coupling with CLM3.5, particularly in summer. Radiation fluxes as well as turbulent fluxes at the surface are found to be more realistically represented in COSMO-CLM². This subsequently leads to improvements of several aspects of the simulated climate (cloud cover, surface temperature and precipitation). We show that a better partitioning of turbulent fluxes is the central factor allowing for the better performances of COSMO-CLM² over COSMO-CLM. Despite these improvements, some model deficiencies still remain, most notably a substantial underestimation of surface net shortwave radiation. Overall, these results highlight the importance of land surface processes in shaping the European climate and the benefit of using an advanced land surface model for regional climate simulations.  相似文献   

The Miocene Costa Giardini diatreme,Iblean Mountains,southern Italy: model for maar-diatreme formation on a submerged carbonate platform     

Sonia Calvari  Lawrence H. Tanner 《Bulletin of Volcanology》2011,73(5):557-576

In this paper we present a model for the growth of a maar-diatreme complex in a shallow marine environment. The Miocene-age Costa Giardini diatreme near Sortino, in the region of the Iblei Mountains of southern Sicily, has an outer tuff ring formed by the accumulation of debris flows and surge deposits during hydromagmatic eruptions. Vesicular lava clasts, accretionary lapilli and bombs in the older ejecta indicate that initial eruptions were of gas-rich magma. Abundant xenoliths in the upper, late-deposited beds of the ring suggest rapid magma ascent, and deepening of the eruptive vent is shown by the change in slope of the country rock. The interior of the diatreme contains nonbedded breccia composed of both volcanic and country rock clasts of variable size and amount. The occurrence of bedded hyaloclastite breccia in an isolated outcrop in the middle-lower part of the diatreme suggests subaqueous effusion at a low rate following the end of explosive activity. Intrusions of nonvesicular magma, forming plugs and dikes, occur on the western side of the diatreme, and at the margins, close to the contact between breccia deposits and country rock; they indicate involvement of volatile-poor magma, possibly during late stages of activity. We propose that initial hydromagmatic explosive activity occurred in a shallow marine environment and the ejecta created a rampart that isolated for a short time the inner crater from the surrounding marine environment. This allowed explosive activity to draw down the water table in the vicinity of the vent and caused deepening of the explosive center. A subsequent decrease in the effusion rate and cessation of explosive eruptions allowed the crater to refill with water, at which time the hyaloclastite was deposited. Emplacement of dikes and plugs occurred nonexplosively while the breccia sediment was mostly still soft and unconsolidated, locally forming peperites. The sheltered, low-energy lagoon filled with marine limestones mixed with volcaniclastic material eroded from the surrounding ramparts. Ultimately, lagoonal sediments accumulated in the crater until subsidence or erosion of the tuff ring caused a return to normal shallow marine conditions.  相似文献   

Degradation and Detoxification of Chlorophenols in Continuous‐Flow Fixed‐Bed Aerobic Reactors     

Alfredo Gallego  Virginia L. Gemini  Susana L. Rossi  Carlos E. Gómez  Gustavo D. Bulus Rossini  Sonia E. Korol 《洁净——土壤、空气、水》2011,39(8):774-780

An indigenous bacterial strain of Delftia sp. capable of degrading 2,4‐dicholorophenol and an indigenous bacterial community that degrades 2,4,6‐trichlorophenol (TCP) were employed to inoculate continuous down‐flow fixed‐bed reactors. Continuous‐reactors were constructed from PVC employing hollow PVC cylinders as support material. Synthetic wastewater was prepared by dissolving the corresponding chlorophenol in non‐sterile groundwater. Biodegradation was evaluated by spectrophotometry, chloride release, GC, and microbial growth. Detoxification was evaluated by using Daphnia magna as test organism. Delftia sp. was able to remove an average of 95.6% of DCP. Efficiency in terms of chemical oxygen demand (COD) was of 88.9%. The indigenous bacterial community that degrades TCP reached an average efficiency of 96.5 and 91.6% in terms of compound and COD removal, respectively. In both cases stoichiometric removal of chloride and detoxification was achieved. When synthetic wastewater feed was cut off for 7 days, both reactors showed a fast recovery after inflow restarting, reaching average outlet concentration values within 36 h. The promising behavior of the microorganisms and the low cost of the reactors tested allow us to suggest their possible application to remediation processes.  相似文献   

Cotton Fiber/ZrO2, A New Material for Adsorption of Cr(VI) Ions in Water     

Alfredo Alberto Muxel  Sonia Maria Nobre Gimenez  Flaveli Aparecida de Souza Almeida  Rení Ventura da Silva Alfaya  Antonio Alberto da Silva Alfaya 《洁净——土壤、空气、水》2011,39(3):289-295

The natural cotton fiber was used to synthesize an anion exchange, containing ZrO₂ film on its surface, NCFZC (natural cotton fiber/ZrO₂ composite). This anion exchanger was produced by the reaction of the zirconium oxychloride and hydroxyl groups on surface of the natural cotton fiber. The material was used for Cr(VI) ions adsorption studies. Adsorption equilibrium time and optimum pH for Cr(VI) adsorption were found to be 6 h and 4.0, respectively. The Langmuir and Temkin isotherms were used to models adsorption equilibrium data. The adsorption capacity of NCFZC was found to be 1.33 mmol/g. Kinetic studies showed that the rate of adsorption of Cr(VI) on NCFZC obeyed a pseudo‐second‐order kinetic model.  相似文献   

Subduction erosion of forearc mantle wedge implicated in the genesis of the South Sandwich Island (SSI) arc: Evidence from boron isotope systematics     

Sonia Tonarini  William P. Leeman  Phil T. Leat 《Earth and Planetary Science Letters》2011,301(1-2):275-284

The South Sandwich volcanic arc is sited on a young oceanic crust, erupts low-K tholeiitic rocks, is characterized by unexotic pelagic and volcanogenic sediments on the down-going slab, and simple tectonic setting, and is ideal for assessing element transport through subduction zones. As a means of quantifying processes attending transfer of subduction-related fluids from the slab to the mantle wedge, boron concentrations and isotopic compositions were determined for representative lavas from along the arc. The samples show variable fluid-mobile/fluid-immobile element ratios and high enrichments of B/Nb (2.7 to 55) and B/Zr (0.12 to 0.57), similar to those observed in western Pacific arcs. δ¹¹B values are among the highest so far reported for mantle-derived lavas; these are highest in the central part of the arc (+ 15 to + 18‰) and decrease toward the southern and northern ends (+ 12 to + 14‰). δ¹¹B is roughly positively correlated with B concentrations and with ⁸⁷Sr/⁸⁶Sr ratios, but poorly coupled with other fluid-mobile elements such as Rb, Ba, Sr and U. Peridotites dredged from the forearc trench also have high δ¹¹B (ca. + 10‰) and elevated B contents (38–140 ppm). Incoming pelagic sediments sampled at ODP Site 701 display a wide range in δ¹¹B (+ 5 to ? 13‰; average = ? 4.1‰), with negative values most common. The unusually high δ¹¹B values inferred for the South Sandwich mantle wedge cannot easily be attributed to direct incorporation of subducting slab materials or fluids derived directly therefrom. Rather, the heavy B isotopic signature of the magma sources is more plausibly explained by ingress of fluids derived from subduction erosion of altered frontal arc mantle wedge materials similar to those in the Marianas forearc. We propose that multi-stage recycling of high-δ¹¹B and high-B serpentinite (possibly embellished by arc crust and volcaniclastic sediments) can produce extremely ¹¹B-rich fluids at slab depths beneath the volcanic arc. Infiltration of such fluids into the mantle wedge likely accounts for the unusual magma sources inferred for this arc.  相似文献   

The influence of recultivation technique and seed mixture on erosion stability after restoration in mountain environment     

Bernhard Krautzer  Wilhelm Graiss  Giovanni Peratoner  Christian Partl  Sonia Venerus  Brigitte Klug 《Natural Hazards》2011,56(2):547-557

Control of erosion, and all of its after effects, from increased surface drainage and erosion to the formation of karst, is one of the essential problems when undertaking recultivation following necessary interventions in the sub-alpine and alpine vegetation stage (high zones). Average slope inclinations of 30–45% in the vicinity of ski runs, and far above in areas of natural erosion and avalanche zones, make restoration processes with sufficient erosion protection the prerequisite for success. Only a sufficient vegetation development of more than 70% ground cover stabilises the topsoil in the long term and reduces soil erosion to an acceptable degree. From 1999 to 2002, an international EU project with the participation of research groups and private firms from Austria, Italy and Germany was carried out under the direction of the Agricultural Research and Education Centre Raumberg-Gumpenstein (AREC) on five different Alpine sites at altitudes from 1,245 to 2,350 m above sea level. The aim of the work was the formulation of practice-relevant requirements for recultivation following intervention in high zones, especially following constructional measures in the vicinity of ski runs and lifts, torrent- and avalanche barriers. In a statistical comparison, the relationship between restoration techniques, seed mixtures of differing ecological value and vegetation cover was observed. The influence of application technique on erosion processes after restoration was obvious for the first two vegetation periods. Only with the additional use of mulch covers could increase surface drainage and noticeable soil loss be avoided. At high altitudes, the choice of seed mixture, irrespective of whether rapid or slow growing and independent of the extent of accompanying fertilisation, had no significance in the first two vegetation periods following sowing. In the following growing seasons, however, higher cover values were obtained with site-specific seed mixtures at three of the five experimental sites. While few species of the commercial seed mixture showed satisfactory persistency, most of the grasses and in particular the alpine leguminosae of site-specific seed mixtures increased their share during the observation period. In the long-term, sufficient protection against erosion is only guaranteed by the use of stable, enduring and ecologically adapted species.  相似文献